Diethylene Glycol → HCID 86743027, compound

HRID 1761980Notes

Reaction equation

HRID 1761980 reaction equation
[CH2:1]([OH:7])[CH2:2][O:3][CH2:4][CH2:5][OH:6].[N+:8]([C:11]1[CH:19]=[CH:18][C:14]([C:15](Cl)=[O:16])=[CH:13][CH:12]=1)([O-:10])=[O:9]>>[N+:8]([C:11]1[CH:19]=[CH:18][C:14]([C:15]([C:1]([OH:7])([C:15](=[O:16])[C:14]2[CH:13]=[CH:12][C:11]([N+:8]([O-:10])=[O:9])=[CH:19][CH:18]=2)[CH2:2][O:3][CH2:4][CH2:5][OH:6])=[O:16])=[CH:13][CH:12]=1)([O-:10])=[O:9]

Participants

3

Reactant 2

HCID 8117Diethylene GlycolHCID 85024-Nitrobenzoyl chloride

Product 1

HCID 86743027HCID 86743027, compoundYield 83.3%

Procedure

Diethylene glycol (31.8 g, 0.3 mole) and p-nitrobenzoyl chloride (116 g, 0.62 mole) were reacted under the conditions described in Example 1, Part A. The product was crystallized from ethyl acetate to give bis-(4-nitrobenzoyl)-diethylene glycol (101 g) as a pale yellow solid, m.p. 100°-102° C. The product was homogeneous by TLC.

Workup

  1. customThe product was crystallized from ethyl acetate

Sources & evidence

ORD record
ord-94871ac009784dadb5313817ca971116
Source dataset
uspto-grants-1989_05
Patent number
US04829099

Reaction notes

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