Methyl iodide → HCID 19828875, compound

HRID 1761990Notes

Reaction equation

HRID 1761990 reaction equation
[CH:1]1([P:7]([CH:14]2[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15]2)[CH:8]2[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]2)[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[I:20]C>[I-].C[P+](C1CCCCC1)(C1CCCCC1)C1CCCCC1.C1CCCCC1>[I-:20].[CH:14]1([PH+:7]([CH:1]2[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]2)[CH:8]2[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]2)[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]1

Participants

5

Reactant 2

HCID 6328Methyl iodide2×HCID 75806Tricyclohexylphosphine2×

Product 1

HCID 19828875HCID 19828875, compound

Reagents, catalysts & solvents 2

HCID 20043900HCID 20043900, compoundCatalystHCID 8078CyclohexaneSolvent

Procedure

This example shows the storage stability of precatalyzed resin containing methyl tricyclohexyl phosphonium iodide catalyst. Tricyclohexyl phosphonium iodide was prepared by reacting tricyclohexylphosphine with iodomethane. 3.95 g of tricyclohexyl phosphine was charged to a 200-ml flask. 70 ml of cyclohexane was added. The resulting solution was maintained with stirring under a nitrogen blanket and condenser. 2 g of iodomethane was added to the solution, resulting in the precipitation of a white solid. The reaction mixture was vacuum filtered and dried in a vacuum oven.

Workup

  1. temperatureThe resulting solution was maintained
  2. customresulting in the precipitation of a white solid
  3. filtrationfiltered
  4. customdried in a vacuum oven

Sources & evidence

ORD record
ord-ccc9492698364c08bed1a33f55d9c071
Source dataset
uspto-grants-1989_05
Patent number
US04829141

Reaction notes

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