Sodium peroxide → Bis(11-acetoxyundecanoyl)peroxide

HRID 1762356Notes

Reaction equation

HRID 1762356 reaction equation
[C:1]([O:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][C:15](Cl)=[O:16])(=[O:3])[CH3:2].[O-:18][O-:19].[Na+].[Na+]>>[C:1]([O:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][C:15]([O:18][O:19][C:15](=[O:16])[CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][O:4][C:1](=[O:3])[CH3:2])=[O:16])(=[O:3])[CH3:2]

Participants

3

Reactant 2

HCID 14803Sodium peroxideHCID 1311378611-Chloro-11-oxoundecyl acetate

Product 1

HCID 14424131Bis(11-acetoxyundecanoyl)peroxide

Procedure

In 50 ml of petroleum ether was dissolved 10.5 g of 11-acetoxyundecanoylchloride. To the solution was added 20 ml of ice-water. To the mixture was further added, while stirring, 4 g of sodium peroxide little by little. The organic layer was separated, and the aqueous layer was subjected to extraction with ether. The organic layer and the ether extracts were combined, washed with water and dried, followed by evaporation of the solvent to yield 8.6 g of white wax-like bis(11-acetoxyundecanoyl)peroxide.

Workup

  1. additionTo the mixture was further added
  2. customThe organic layer was separated
  3. extractionthe aqueous layer was subjected to extraction with ether
  4. washwashed with water
  5. customdried
  6. customfollowed by evaporation of the solvent

Sources & evidence

ORD record
ord-0094cfefebe34d69ad699ab448e12f49
Source dataset
uspto-grants-1989_05
Patent number
US04831265

Reaction notes

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