HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Anhydride → HCID 54537209, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Anhydride | HCID 7918 | — |
| Reactant | 9-amino-11-(3-dimethylaminopropylidene)-11H-pyrrolo[2,1-b][3]benzazepine | HCID 53755083 | — |
| Solvent | Pyridine | HCID 1049 | — |
| Product | HCID 54537209 | HCID 54537209 | — |
Reaction Steps
9-Amino-11-(3-dimethylaminopropylidene)-11H-pyrrolo[2,1-b][3]benzazepine (11.4 mmoles) dissolved in 15 ml. pyridine is treated with acetic anhydride (2 ml.) at room temperature for 19 hours. The volatiles are removed under vacuum and the residue is dissolved in chloroform, and chromatographed on silica gel. Elution with chloroform-methanol yields 9-acetamido-11-(3-dimethylaminopropylidene)-11H-pyrrolo[2,1-b][3]benzazepine.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04112112 |
| Source dataset | uspto-grants-1978_09 |
| ORD ID | ord-b329555e2517467999cd936365be851d |
| Source note | uspto-grants-1978_09 |