HRID1766189
反应详情
EQUATION
反应方程式
REACTANTS
反应物
PRODUCTS
生成物
AUXILIARIES
试剂、催化剂与溶剂
PROCEDURE
实验过程
A mixture of 75 g (0.235 mol) of 1-(diphenylmethyl)-3-(methanesulphonyloxy)-azetidine, 47.1 g (0.254 mol) of potassium phthalimide and 800 ml of dimethylformamide was refluxed for 1½ hours, during which time a fine precipitate gradually settled out. After cooling the precipitate was filtered off and the solvent was evaporated off in vacuo, finally under a high vacuum. The colourless residue crystallised when left to stand. Yield: 78.0 g (90% of theoretical). Rf=0.95 (El N).
WORKUP
后处理
- temperaturewas refluxed for 1½ hours, during which time a fine precipitate
- temperatureAfter cooling the precipitate
- filtrationwas filtered off
- customthe solvent was evaporated off in vacuo, finally under a high vacuum
- customThe colourless residue crystallised when
- waitleft