Hydrochloric Acid → (2E)-2-methoxyimino-N-methyl-2-(2-phenoxyphenyl)acetamide

HRID 1769422Notes

Reaction equation

HRID 1769422 reaction equation
[CH3:1][O:2]/[N:3]=[C:4](/[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=1[O:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)\[C:5]([NH:7][CH3:8])=[O:6].Cl>CO>[CH3:1][O:2]/[N:3]=[C:4](\[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=1[O:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)/[C:5]([NH:7][CH3:8])=[O:6]

Participants

4

Reactant 2

HCID 313Hydrochloric AcidHCID 9576038(Z)-Metominostrobin

Product 1

HCID 5483872(2E)-2-methoxyimino-N-methyl-2-(2-phenoxyphenyl)acetamide

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent2×

Procedure

To Z-2-methoxyimino-N-methyl-2-(2phenoxyphenyl)acetamide VI" (0.28 g, 1.0 mmole) were added dried methanol (3 ml) and 10% hydrochloric acid solution in methanol (0.36 g, 1.0 mmole) and the mixture was heated under reflux for 6 hours to conduct isomerization.

Workup

  1. temperaturethe mixture was heated
  2. temperatureunder reflux for 6 hours

Sources & evidence

ORD record
ord-4192ae6a7b1045aebb00bd10cd1a198d
Source dataset
uspto-grants-1995_01
Patent number
US05380913

Reaction notes

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