HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Hexene → 4,4-Dichloro-2-phenyl-4-siladecane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Hexene | HCID 11597 | — |
| Reactant | 3-Phenyl-1,1-dichloro-1-silabutane | HCID 123324342 | — |
| Catalyst | Chloroplatinic acid | HCID 61859 | — |
| Solvent | Isopropanol | HCID 3776 | — |
| Product | 4,4-Dichloro-2-phenyl-4-siladecane | HCID 21841446 | 60.6% |
Reaction Steps
in the same apparatus and procedures as EXAMPLE 1, 5.0 g (0.023 mole) of 3-phenyl-1,1-dichloro-1-silabutane, 5.8 g (0.07 mole) of 1-hexene, and 100 μl of 1% chloroplatinic acid in isopropanol were placed and reacted under the dry nitrogen atmosphere. Vacuum distillation of the reaction products gave 4.23 g (bp, 115°-8° C./0.6 mmHg) of 4,4-dichloro-2-phenyl-4-siladecane.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05386050 |
| Source dataset | uspto-grants-1995_01 |
| ORD ID | ord-f3bde85830fd459c8dc633004235f479 |
| Source note | uspto-grants-1995_01 |