1-Hexene → 4,4-Dichloro-2-phenyl-4-siladecane

HRID 1770329Notes

Reaction equation

HRID 1770329 reaction equation
[C:1]1([CH:7]([CH3:12])[CH2:8][SiH:9]([Cl:11])[Cl:10])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:13]=[CH:14][CH2:15][CH2:16][CH2:17][CH3:18]>C(O)(C)C.[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl>[Cl:10][Si:9]([Cl:11])([CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])[CH2:8][CH:7]([C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)[CH3:12]

Participants

5

Reactant 2

HCID 115971-HexeneHCID 1233243423-Phenyl-1,1-dichloro-1-silabutane

Product 1

HCID 218414464,4-Dichloro-2-phenyl-4-siladecaneYield 60.6%

Reagents, catalysts & solvents 2

HCID 61859Chloroplatinic acidCatalystHCID 3776IsopropanolSolvent

Procedure

in the same apparatus and procedures as EXAMPLE 1, 5.0 g (0.023 mole) of 3-phenyl-1,1-dichloro-1-silabutane, 5.8 g (0.07 mole) of 1-hexene, and 100 μl of 1% chloroplatinic acid in isopropanol were placed and reacted under the dry nitrogen atmosphere. Vacuum distillation of the reaction products gave 4.23 g (bp, 115°-8° C./0.6 mmHg) of 4,4-dichloro-2-phenyl-4-siladecane.

Workup

  1. customreacted under the dry nitrogen atmosphere
  2. distillationVacuum distillation of the reaction products

Sources & evidence

ORD record
ord-f3bde85830fd459c8dc633004235f479
Source dataset
uspto-grants-1995_01
Patent number
US05386050

Reaction notes

Loading…