HuagongsheHuagongshe Chemistry Print Report · For research reference only
3,6-Dimethyl-2-pyridinamine → HCID 178425974, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3,6-Dimethyl-2-pyridinamine | HCID 578956 | — |
| Reactant | O-(2,4,6-Trimethylbenzenesulfonyl)hydroxylamine | HCID 11830845 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 178425974 | HCID 178425974 | — |
Reaction Steps
A solution of O-(mesitylsulfonyl)hydroxylamine (5.3 g, 24.6 mmol) in DCM (20 mL) was slowly added to a solution of 3,6-dimethylpyridin-2-amine (1.0 g, 8.2 mmol) in DCM (5 mL). A yellow precipitate was formed gradually, and after stirring for 1 h, the precipitate was collected by filtration and used for the next step without further purification. ESI MS: m/z 138 [M+H]+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09249162B2 |
| Source dataset | uspto-grants-2016_02 |
| ORD ID | ord-0c8a4440866e474caeeafb8e84ea9576 |
| Source note | uspto-grants-2016_02 |