tert-Butyl hydroperoxide → (17-Acetyloxy-10,13-dimethyl-7-oxo-1,2,3,4,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-3-yl) acetate

HRID 177291Notes

Reaction equation

HRID 177291 reaction equation
[C:1]([CH3:2])(=[O:3])[O:4][CH:5]1[CH2:6][C:7]2=[CH:8][CH2:9][CH:10]3[CH:11]4[CH2:12][CH2:13][CH:14]([O:24][C:25]([CH3:26])=[O:27])[C:15]4([CH3:16])[CH2:17][CH2:18][CH:19]3[C:20]2([CH3:23])[CH2:21][CH2:22]1.[C:28]([CH3:30])([CH3:31])([O:32][OH:29])[CH3:33]>>[C:1]([CH3:2])(=[O:3])[O:4][CH:5]1[CH2:6][C:7]2=[CH:8][C:9](=[O:32])[CH:10]3[CH:11]4[CH2:12][CH2:13][CH:14]([O:24][C:25]([CH3:26])=[O:27])[C:15]4([CH3:16])[CH2:17][CH2:18][CH:19]3[C:20]2([CH3:23])[CH2:21][CH2:22]1

Participants

3

Reactant 2

HCID 6410tert-Butyl hydroperoxideHCID 540889(17-acetyloxy-10,13-dimethyl-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-3-yl) acetate

Product 1

HCID 273127(17-Acetyloxy-10,13-dimethyl-7-oxo-1,2,3,4,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-3-yl) acetate

Sources & evidence

ORD record
ord-9f4950a98669483c970eb09b62dcf71f
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Reaction notes

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