Sodium aluminate → HCID 20332886, compound

HRID 1773114Notes

Reaction equation

HRID 1773114 reaction equation
[C:1]12([CH2:11][S:12]([OH:15])(=[O:14])=[O:13])[C:8]([CH3:10])([CH3:9])[CH:5]([CH2:6][CH2:7]1)[CH2:4][C:2]2=[O:3].O=[Al-:17]=O.[Na+]>>[C:1]12([CH2:11][S:12]([O-:15])(=[O:13])=[O:14])[C:8]([CH3:10])([CH3:9])[CH:5]([CH2:6][CH2:7]1)[CH2:4][C:2]2=[O:3].[Al+3:17].[C:1]12([CH2:11][S:12]([O-:15])(=[O:13])=[O:14])[C:8]([CH3:10])([CH3:9])[CH:5]([CH2:6][CH2:7]1)[CH2:4][C:2]2=[O:3].[C:1]12([CH2:11][S:12]([O-:15])(=[O:13])=[O:14])[C:8]([CH3:10])([CH3:9])[CH:5]([CH2:6][CH2:7]1)[CH2:4][C:2]2=[O:3]

Participants

3

Reactant 2

HCID 14766Sodium aluminateHCID 18462Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S)-

Product 1

HCID 20332886HCID 20332886, compound

Procedure

To the amine in the sodium aluminate example above, camphorsulfonic acid was added to bring the pH to the range of 7.5-9. The insoluble precipitate that formed was filtered before use. The control did not require any acid addition.

Workup

  1. customThe insoluble precipitate that formed
  2. filtrationwas filtered before use
  3. additionany acid addition

Sources & evidence

ORD record
ord-dc98b5eebd6b474dbf4b18ce21829ea9
Source dataset
uspto-grants-2016_02
Patent number
US09254465B2

Reaction notes

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