HCID 102189385, compound → HCID 87145216, compound

HRID 1775426Notes

Reaction equation

HRID 1775426 reaction equation
C1(SC2C3C=CC=CC=3SC=2I)C=CC=CC=1.[C:18]1([Se:24][C:25]2[C:26]3[CH:34]=[CH:33][CH:32]=[CH:31][C:27]=3[S:28][C:29]=2I)[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1>>[CH:23]1[C:18]2[Se:24][C:25]3[C:26]4[CH:34]=[CH:33][CH:32]=[CH:31][C:27]=4[S:28][C:29]=3[C:19]=2[CH:20]=[CH:21][CH:22]=1

Participants

3

Reactant 2

HCID 102189385HCID 102189385, compoundHCID 131734742HCID 131734742, compound

Product 1

HCID 87145216HCID 87145216, compoundYield 85%

Procedure

Except that 3-(phenylsulfenyl)-2-iodobenzo[b]thiophene was replaced with 3-(phenylselenenyl)-2-iodobenzo[b]thiophene, the reaction was implemented in the same way as in Example 3. Purification was implemented by column chromatography (silica gel, CHCl3, Rf: 0.9), so that a yellow solid was produced (yield: 85%).

Workup

  1. customPurification
  2. customwas produced (yield: 85%)

Sources & evidence

ORD record
ord-1c0158f47b434c0ebc840590c79f3e43
Source dataset
uspto-grants-2016_02
Patent number
US09260451B2

Reaction notes

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