Hydrochloric Acid → HCID 22015055, compound

HRID 1779532Notes

Reaction equation

HRID 1779532 reaction equation
[CH2:1]([N:3](C(OC(C)(C)C)=O)[CH2:4][CH2:5][CH2:6][N:7](C(OC(C)(C)C)=O)[CH2:8]/[CH:9]=[CH:10]/[CH2:11][N:12](C(OC(C)(C)C)=O)[CH2:13][CH2:14][CH2:15][N:16]([CH2:24][CH3:25])C(OC(C)(C)C)=O)[CH3:2].[ClH:47]>C(OCC)C>[ClH:47].[ClH:47].[ClH:47].[ClH:47].[CH2:24]([NH:16][CH2:15][CH2:14][CH2:13][NH:12][CH2:11]/[CH:10]=[CH:9]/[CH2:8][NH:7][CH2:6][CH2:5][CH2:4][NH:3][CH2:1][CH3:2])[CH3:25]

Participants

4

Reactant 2

HCID 313Hydrochloric AcidHCID 19956424HCID 19956424, compound

Product 1

HCID 22015055HCID 22015055, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

1.97 g (3 mmol) of (E)-1,14-di-ethyl-1,5,10,14-tetra-BOC-1,5,10,14-tetraazatetradec-7-ene and 30 ml of 3N methanolic hydrochloric acid are reacted analogously to Example 1. The addition of 50 ml of diethyl ether to the reaction mixture and subsequent filtration yield the title compound, m.p. >260° C. 1H-NMR (D2O): δ1.28(t,6H); 2.04-2.15(m,4H); 3.08-3.19(m,12H); 3.76(d,4H); 6.04-6.07(m,2H).

Workup

  1. filtrationto the reaction mixture and subsequent filtration

Sources & evidence

ORD record
ord-4f015f03e9a64cc39ac921f30a891962
Source dataset
uspto-grants-1997_05
Patent number
US05627215

Reaction notes

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