Hydrochloric Acid → HCID 76309304, compound

HRID 1779714Notes

Reaction equation

HRID 1779714 reaction equation
[O:1]([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[C:14](=[N:18][O:19][CH3:20])[C:15]([NH2:17])=[O:16])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Cl>C1(C)C=CC=CC=1>[O:1]([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1/[C:14](=[N:18]\[O:19][CH3:20])/[C:15]([NH2:17])=[O:16])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

4

Reactant 2

HCID 313Hydrochloric AcidHCID 539671372-(2-Phenoxyphenyl)-2-methoxyiminoacetamide

Product 1

HCID 76309304HCID 76309304, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Conditions

Temperature
80 °C

Procedure

2-(2-phenoxyphenyl)-2-methoxyiminoacetamide (E/Z=14/86) (0.27 g, 1 mmol) was dissolved in toluene (1 ml). Conc. hydrochloric acid (0.17 ml) was added, and the mixture was heated at 80° C. for 2 hours. A part of the mixture was sampled, and the toluene was evaporated under reduced pressure to give (E)-2-(2-phenoxyphenyl)-2-methoxyiminoacetamide. The E/Z ratio of it was determined (E/Z=98/2).

Workup

  1. aliquotA part of the mixture was sampled
  2. customthe toluene was evaporated under reduced pressure

Sources & evidence

ORD record
ord-9769bac4a5ab45358063a87114078829
Source dataset
uspto-grants-1997_05
Patent number
US05627284

Reaction notes

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