HRID1780620

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6348

Carbon disulfide

CS2

HCID16316

Dipentylamine

C10H23N

HCID18008153

未命名化合物

结构：CCCCC(CC)CC(=O)[O-].CCCCC(CC)CC(=O)[O-].CCCCC(CC)CC(=O)[O-].[Bi+3]

HCID22107642

未命名化合物

PRODUCTS

生成物

HCID68156

2-Imidazoline

C3H6N2

HCID21832312

未命名化合物

结构：CCCCCN(CCCCC)C(=S)[S-].CCCCCN(CCCCC)C(=S)[S-].CCCCCN(CCCCC)C(=S)[S-].[Bi+3]

HCID23437600

未命名化合物

CONDITIONS

反应条件

温度: 80 °C

PROCEDURE

实验过程

A reaction vessel was charged with diamylamine, 65.2 g, tall oil 1-hydroxyethyl-2-imidazoline, 145 g, and bismuth 2-ehtylhexyl-carboxylate, 103.3 g. Carbon disulfide, 45 g, was charged with cooling to control the exothermic reaction and then was maintained at 80° C. The reaction was stripped under vacuum to yield bismuth diamyldithiocarbamate and imidazoline salt of 2-ethylhexyl-carboxylate.

WORKUP

后处理

temperaturewith cooling
customthe exothermic reaction

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-f4c7eafe84fa4d3aa64495a23577d41a
来源数据集: uspto-grants-1997_05
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05631214
来源说明: uspto-grants-1997_05

反应 SMILES

[CH2:1]([NH:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:2][CH2:3][CH2:4][CH3:5].OC([N:15]1[CH2:19][CH2:18][N:17]=[CH:16]1)C.[CH2:20]([CH:22]([CH2:27][CH2:28][CH2:29][CH3:30])[CH2:23][C:24]([O-:26])=[O:25])[CH3:21].[Bi+3:31].C(C(CCCC)CC([O-])=O)C.C(C(CCCC)CC([O-])=O)C.[C:54](=[S:56])=[S:55]>>[CH2:7]([N:6]([CH2:1][CH2:2][CH2:3][CH2:4][CH3:5])[C:54](=[S:55])[S-:56])[CH2:8][CH2:9][CH2:10][CH3:11].[Bi+3:31].[CH2:7]([N:6]([CH2:1][CH2:2][CH2:3][CH2:4][CH3:5])[C:54](=[S:55])[S-:56])[CH2:8][CH2:9][CH2:10][CH3:11].[CH2:7]([N:6]([CH2:1][CH2:2][CH2:3][CH2:4][CH3:5])[C:54](=[S:55])[S-:56])[CH2:8][CH2:9][CH2:10][CH3:11].[NH:17]1[CH2:18][CH2:19][N:15]=[CH:16]1.[CH2:20]([CH:22]([CH2:27][CH2:28][CH2:29][CH3:30])[CH2:23][C:24]([O-:26])=[O:25])[CH3:21]