Acetic Anhydride → 2,2-Dimethylphenethyl acetate

HRID 1781102ノート

反応式

HRID 1781102 の反応式
[CH3:1][C:2]1([CH3:11])[CH:10]=[CH:9][CH:8]=[CH:7][CH:3]1[CH2:4][CH2:5][OH:6].[C:12](OC(=O)C)(=[O:14])[CH3:13]>N1C=CC=CC=1>[C:12]([O:6][CH2:5][CH2:4][CH:3]1[CH:7]=[CH:8][CH:9]=[CH:10][C:2]1([CH3:11])[CH3:1])(=[O:14])[CH3:13]

参加物

4

反応物 2

HCID 7918Acetic AnhydrideHCID 701452672,2-Dimethylphenethyl alcohol

生成物 1

HCID 229063012,2-Dimethylphenethyl acetate

試薬・触媒・溶媒 1

HCID 1049Pyridine溶媒

実験手順

Dissolve 2,2-dimethylphenethyl alcohol (118.0 g, 0.786 mol) in pyridine (700 mL). Add, by dropwise addition, acetic anhydride (222 mL, 240.7 g, 2.358 mol) and stir overnight at room temperature. Evaporate the solvent in vacuo and purify by distillation to give the title compound as a clear colorless oil; bp 75° C. @ 0.4 mmHg.

後処理

  1. customEvaporate the solvent in vacuo
  2. distillationpurify by distillation

出典と根拠

ORDレコード
ord-387912939de7416b9e56f5247a2569aa
出典データセット
uspto-grants-1997_05
特許番号
US05631375

反応ノート

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