2-Acetylhydroquinone → HCID 19045447, compound

HRID 1781431Notes

Reaction equation

HRID 1781431 reaction equation
[OH:1][C:2]1[CH:7]=[CH:6][C:5](O)=[CH:4][C:3]=1[C:9](=[O:11])[CH3:10].[C:12]([N:15]1[CH2:20][CH2:19][C:18](=[O:21])[CH2:17][CH2:16]1)(=[O:14])[CH3:13]>CCOC(C)=O.CCCCCC>[C:12]([N:15]1[CH2:20][CH2:19][C:18]2([CH2:10][C:9](=[O:11])[C:3]3[C:2]([OH:1])=[CH:7][CH:6]=[CH:5][C:4]=3[O:21]2)[CH2:17][CH2:16]1)(=[O:14])[CH3:13]

Participants

4

Reactant 2

HCID 102792-AcetylhydroquinoneHCID 122563N-Acetyl-4-piperidone

Product 1

HCID 19045447HCID 19045447, compound

Reagents, catalysts & solvents 1

HCID 21226206Ethyl acetate hexaneSolvent

Procedure

2',5'-Dihydroxyacetophenone and 1-acetyl-4-piperidone were condensed according to the method of Example 434 to give the ketone as a yellow solid, m.p. 114°-116° C. (from EtOAc/hexane).

Workup

  1. customcondensed

Sources & evidence

ORD record
ord-533498180d604b9bb47605586215ea6f
Source dataset
uspto-grants-1997_05
Patent number
US05633247

Reaction notes

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