HuagongsheHuagongshe Chemistry Print Report · For research reference only
Isoamyl Nitrite → 6-Methyl-2-hydroxyimino-1-indanone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Isoamyl Nitrite | HCID 8053 | — |
| Reactant | 6-Methyl-1-indanone | HCID 2795093 | — |
| Reactant | 1,4-Dioxane hydrochloride | HCID 20443148 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 6-Methyl-2-hydroxyimino-1-indanone | HCID 58717336 | — |
Reaction Steps
6-Methyl-1-indanone (40.4 g) and isoamyl nitrite (40.6 mL) were dissolved in ethanol (300 mL), and 4N hydrogen chloride-dioxane (10 mL) was added dropwise under ice-cooling. After the completion of the reaction, the precipitated crystals were collected by filtration and washed with ether to give 6-methyl-2-hydroxyimino-1-indanone (37 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07501412B2 |
| Source dataset | uspto-grants-2009_03 |
| ORD ID | ord-7d49fe7db0444eacaa2175ac7a59ed16 |
| Source note | uspto-grants-2009_03 |