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HRID1783879

反应详情

EQUATION

反应方程式

HRID 1783879 的结构方程式

REACTANTS

反应物

2
结构：[Li+].[OH-]
HCID3939

Lithium hydroxide anhydrous

HLiO

结构：COC(=O)[C@@H](O)CSCc1ccccc1
HCID59639322

未命名化合物

PRODUCTS

生成物

1
结构：O=C(O)[C@@H](O)CSCc1ccccc1
HCID10059030

(R)-3-Benzylsulfanyl-2-hydroxy-propionic acid

C10H12O3S

收率 46%

PROCEDURE

实验过程

This reaction was performed as previously described by Deechongkit, S.; You, S.-L.; Kelly, J. W. Org. Lett. 2004, 6, 497, using (R)-3-Benzylsulfanyl-2-hydroxy-propionic acid methyl ester 110b and lithium hydroxide. (R)-3-Benzylsulfanyl-2-hydroxy-propionic acid 110c (3.08 g, 14.51 mmol, 46%) was isolated as a viscous oil: MS calcd. for C10H12O3S (M+Na+) 235.1, found 235.3.