Sodium Bicarbonate → HCID 23708851, compound

HRID 1788842Notes

Reaction equation

HRID 1788842 reaction equation
[CH3:1][O:2][C:3]1[CH:30]=[CH:29][C:6]([O:7][C:8]2[S:14][CH:13]3[N:10]([C:11](=[O:15])[CH2:12]3)[C:9]=2[C:16]([O:18]CC2C=CC([N+]([O-])=O)=CC=2)=[O:17])=[CH:5][CH:4]=1.C(=O)(O)[O-].[Na+:35]>O1CCOCC1.O.[Pd]>[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]([O:7][C:8]2[S:14][CH:13]3[N:10]([C:11](=[O:15])[CH2:12]3)[C:9]=2[C:16]([O-:18])=[O:17])=[CH:29][CH:30]=1.[Na+:35]

Participants

6

Reactant 2

HCID 516892Sodium BicarbonateHCID 13578052HCID 13578052, compound

Product 1

HCID 23708851HCID 23708851, compound

Reagents, catalysts & solvents 3

HCID 23938PalladiumCatalystHCID 962WaterSolventHCID 312751,4-DioxaneSolvent

Procedure

A mixture of a solution of 60 mg of 4-nitrobenzyl 3-(4-methoxyphenoxy)-7-oxo-4-thia-1-azabicyclo[3,2,0]hept-2-ene-2-carboxylate in dioxan and 15 mg of sodium bicarbonate in water, and 10% palladium/charcoal was hydrogenated at 50 psi at 25° for 60 minutes.

Sources & evidence

ORD record
ord-682a8533f4c743c19b88d6287889b659
Source dataset
uspto-grants-1987_08
Patent number
US04684640

Reaction notes

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