Diphenylphosphine → HCID 14007800, compound

HRID 1789260Notes

Reaction equation

HRID 1789260 reaction equation
[CH2:1]([N:4]([CH2:7][CH3:8])[CH2:5][CH3:6])[CH:2]=[CH2:3].[C:9]1([PH:15][C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.C(N(CC)C(C)CP(C1C=CC=CC=1)C1C=CC=CC=1)C>>[CH2:5]([N:4]([CH2:1][CH2:2][CH2:3][P:15]([C:16]1[CH:17]=[CH:18][CH:19]=[CH:20][CH:21]=1)[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[CH2:7][CH3:8])[CH3:6]

Participants

4

Reactant 3

HCID 70017DiphenylphosphineHCID 797482-Propen-1-amine, N,N-diethyl-HCID 20189051HCID 20189051, compound

Product 1

HCID 14007800HCID 14007800, compound

Procedure

A mixture of 17 g (0.15 mole) allyl diethyl amine and 30.7 g (0.165 mole, 10% excess) of diphenyl phosphine is reacted in the usual manner with u.v. irradiation for 17 hours. A subsequent analysis of the reaction mixture indicated that about one third of the reactants was converted. The only product formed was the desired adduct, 2-diethylaminopropyl diphenylphosphine. It was isolated as a clear colorless liquid (Table 4).

Workup

  1. customis reacted in the usual manner with u.v
  2. customirradiation for 17 hours
  3. customThe only product formed
  4. customIt was isolated as a clear colorless liquid (Table 4)

Sources & evidence

ORD record
ord-66a50a8d07224708b09bcfbde3dd4b52
Source dataset
uspto-grants-1987_08
Patent number
US04687866

Reaction notes

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