Bromine → HCID 15338836, compound

HRID 1789396Notes

Reaction equation

HRID 1789396 reaction equation
[Br:1]Br.[CH3:3][C:4]1[C:12]2[C:7](=[CH:8][CH:9]=[C:10]([CH3:13])[CH:11]=2)[CH2:6][C:5]=1[C:14](=[O:16])[CH3:15]>CCOCC>[Br:1][CH2:15][C:14]([C:5]1[CH:4]([CH3:3])[C:12]2[C:7]([CH:6]=1)=[CH:8][CH:9]=[C:10]([CH3:13])[CH:11]=2)=[O:16]

Participants

4

Reactant 2

HCID 24408BromineHCID 20188240HCID 20188240, compound

Product 1

HCID 15338836HCID 15338836, compoundYield 59.5%

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

Bromine (2.80 g) is added to 1-(3,5-dimethyl-inden-2-yl)ethanone (3.00 g) in dry ether (30 ml), while keeping the temperature at +10° C. The mixture is extracted with water, several times with the diluted NaHCO3 solution, again with water, dried and evaporated under reduced pressure to afford the product (2.54 g, 59%).

Workup

  1. customat +10° C
  2. extractionThe mixture is extracted with water, several times with the diluted NaHCO3 solution, again with water
  3. customdried
  4. customevaporated under reduced pressure

Sources & evidence

ORD record
ord-87ac3ca1a6a44205a81100de76b418af
Source dataset
uspto-grants-1987_08
Patent number
US04689339

Reaction notes

Loading…