Toluene → Bis(2-hydroxyphenyl)methane

HRID 1789568Notes

Reaction equation

HRID 1789568 reaction equation
C([O:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)C1OC1.[C:12]1([CH3:18])[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1.CCN(CCCN)CC.CC([OH:31])C>>[CH:9]1[CH:8]=[C:7]([CH2:18][C:12]2[C:17]([OH:31])=[CH:16][CH:15]=[CH:14][CH:13]=2)[C:6]([OH:5])=[CH:11][CH:10]=1

Participants

5

Reactant 4

HCID 1140TolueneHCID 3776IsopropanolHCID 31217Phenyl glycidyl etherHCID 61011N,N-Diethyl-1,3-propanediamine

Product 1

HCID 75575Bis(2-hydroxyphenyl)methane

Procedure

252 g of Adeka Resin EP-4100, 16 g of PGE (phenyl glycidyl ether), 70 g of toluene and 70 g of IPA were added to 132 g of DEAPA and the addition reaction was carried out at 80° to 90° C. for 4 h while the solvent was refluxed. Then, toluene and IPA were distilled out. After thorough distillation of the solvent, a reaction product (A-2) was obtained. This reaction product was mixed with the phenoic novolac (B-1) obtained in Example 1 or bisphenol F in a ratio shown in the following table and a melt masking reaction was carried out at 150° C. for 3 h.

Workup

  1. additionthe addition reaction
  2. temperaturewas refluxed
  3. distillationThen, toluene and IPA were distilled out
  4. distillationAfter thorough distillation of the solvent
  5. customa reaction product (A-2) was obtained
  6. additionThis reaction product was mixed with the phenoic novolac (B-1)

Sources & evidence

ORD record
ord-f299fc50d6c74d1d92fec367d9ed7c37
Source dataset
uspto-grants-1987_08
Patent number
US04689390

Reaction notes

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