Methacrylic Acid → 2-Methyl-2-adamantyl methacrylate

HRID 1790863Notes

Reaction equation

HRID 1790863 reaction equation
[CH3:1][C:2]1([OH:12])[CH:9]2[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:11][CH:3]1[CH2:4]3)[CH2:8]2.[C:13](O)(=[O:16])[CH:14]=[CH2:15].[C:18]([OH:23])(=[O:22])[C:19]([CH3:21])=[CH2:20]>>[C:13]([O:12][C:2]1([CH3:1])[CH:3]2[CH2:11][CH:7]3[CH2:6][CH:5]([CH2:10][CH:9]1[CH2:8]3)[CH2:4]2)(=[O:16])[CH:14]=[CH2:15].[C:18]([O:23][C:2]1([CH3:1])[CH:3]2[CH2:11][CH:7]3[CH2:6][CH:5]([CH2:10][CH:9]1[CH2:8]3)[CH2:4]2)(=[O:22])[C:19]([CH3:21])=[CH2:20]

Participants

5

Reactant 3

HCID 4093Methacrylic AcidHCID 6581Acrylic AcidHCID 1365452-Methyl-2-adamantanol

Product 2

HCID 98375662-Methyl-2-adamantyl methacrylateHCID 112182922-Methyladamantan-2-yl Acrylate (stabilized with MEHQ)

Procedure

For example, by conducting a reaction using, as the 2-alkyl-2-adamantanol, 2-methyl-2-adamantanol and, as the carboxylic acid compound, acrylic acid or methacrylic acid, there is obtained 2-methyl-2-adamantyl acrylate or 2-methyl-2-adamantyl methacrylate.

Sources & evidence

ORD record
ord-a072c99a12e14176be1d8341ca062ead
Source dataset
uspto-grants-2006_07
Patent number
US07071352B2

Reaction notes

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