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HRID1791187

反应详情

EQUATION

反应方程式

HRID 1791187 的结构方程式

REACTANTS

反应物

2
结构：O=P(Cl)(Cl)Cl
HCID24813

Phosphoric trichloride

Cl3OP

结构：CCC(NC(=O)[C@H]1CC[C@@H](C(C)(C)C)CC1)c1nnc(-c2cccc([N+](=O)[O-])c2)[nH]c1=O
HCID178457784

未命名化合物

PRODUCTS

生成物

1
结构：CCc1nc(C2CCC(C(C)(C)C)CC2)n2nc(-c3cccc([N+](=O)[O-])c3)[nH]c(=O)c12
HCID135682038

未命名化合物

PROCEDURE

实验过程

In analogy to the procedure for Example 21A, 5.1 g (11.6 mmol) crude cis-4-tert-butyl-N-{1-[3-(3-nitrophenyl)-5-oxo-4,5-dihydro-1,2,4-triazin-6-yl]propyl}cyclo-hexanecarboxamide (Example 20A), 2.7 g (17.4 mmol) phosphoric trichloride are stirred at reflux for 3 hours and proportionate amounts of the solvents are used.

WORKUP

后处理

  1. temperatureat reflux for 3 hours