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HRID1795622

反应详情

EQUATION

反应方程式

HRID 1795622 的结构方程式

REACTANTS

反应物

2
结构：CC(C)(C)c1cc(CBr)cc(C(C)(C)C)c1
HCID4447507

1-(Bromomethyl)-3,5-di-tert-butylbenzene

C15H23Br

结构：CC(C)C1=CCC(C)(C)c2cc(O)c(Br)cc21
HCID22218215

未命名化合物

2 次

PRODUCTS

生成物

1
结构：CC(C)C1=CCC(C)(C)c2cc(OCc3cc(C(C)(C)C)cc(C(C)(C)C)c3)c(Br)cc21
HCID22218286

未命名化合物

收率 72%

PROCEDURE

实验过程

Following General Procedure O, 3-bromo-5-isopropyl-8,8-dimethyl-7,8-dihydronaphthalen-2-ol (Compound 97, 0.14 g, 0.48 mmol) was reacted with 3,5-di-t-butylbenzylbromide to afford 0.074 g (72%) of the title compound as a yellow solid. PNMR (300 MHz, CDCl3) δ 1.20 (m, 12 H), 1.37 (s, 18 H), 2.15 (d, 2 H, J=4.8 Hz), 2.85 (m, 1 H), 5.20 (s, 2 H), 5.72 (m, 3 H), 6.95 (s, 1 H), 7.40 (m, 3 H), 7.55 (s, 1 H).