1-(Bromomethyl)-3,5-di-tert-butylbenzene → HCID 22218286, compound

Participants

Reaction Steps

Following General Procedure O, 3-bromo-5-isopropyl-8,8-dimethyl-7,8-dihydronaphthalen-2-ol (Compound 97, 0.14 g, 0.48 mmol) was reacted with 3,5-di-t-butylbenzylbromide to afford 0.074 g (72%) of the title compound as a yellow solid. PNMR (300 MHz, CDCl3) δ 1.20 (m, 12 H), 1.37 (s, 18 H), 2.15 (d, 2 H, J=4.8 Hz), 2.85 (m, 1 H), 5.20 (s, 2 H), 5.72 (m, 3 H), 6.95 (s, 1 H), 7.40 (m, 3 H), 7.55 (s, 1 H).

Provenance & Evidence