Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Quinone | HCID 4650 | — |
| Reactant | 1-Hexanol | HCID 8103 | — |
| Reactant | Sodium Persulfate | HCID 62655 | — |
| Catalyst | Silver Nitrate | HCID 24470 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Hexane | HCID 8058 | — |
| Product | HCID 67117052 | HCID 67117052 | — |
Reaction Steps
While stirring at 60° C., a solution of sodium peroxodisulfate (0.01 mol) in water (10 ml) was added to a heterogeneous mixture of silver nitrate (0.2 g) in water (40 ml) and 1,4-benzoquinone (0.01 mol) and 1-hexanol (0.04 mol) in hexane (5 ml). Extraction with diethyl ether followed by vaporization in vacuo yielded a residue which was purified using column chromatography on silica gel (eluting with hexane/diethylether).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US08350038B2 |
|---|
| Source dataset | uspto-grants-2013_01 |
|---|
| ORD ID | ord-b27cedf97af84f45900fe2056df7b4d7 |
|---|
| Source note | uspto-grants-2013_01 |
|---|
