Quinone → HCID 67117052, compound

HRID 1803061Notes

Reaction equation

HRID 1803061 reaction equation
[O-]S(OOS([O-])(=O)=O)(=O)=O.[Na+].[Na+].[C:13]1(=[O:20])[CH:18]=[CH:17][C:16](=[O:19])[CH:15]=[CH:14]1.[CH2:21]([OH:27])[CH2:22][CH2:23][CH2:24][CH2:25][CH3:26]>O.CCCCCC.[N+]([O-])([O-])=O.[Ag+]>[CH2:25]([CH:24]([C:18]1[C:13](=[O:20])[CH:14]=[CH:15][C:16](=[O:19])[CH:17]=1)[CH2:23][CH2:22][CH2:21][OH:27])[CH3:26]

Participants

7

Reactant 3

HCID 4650QuinoneHCID 81031-HexanolHCID 62655Sodium Persulfate

Product 1

HCID 67117052HCID 67117052, compound

Reagents, catalysts & solvents 3

HCID 24470Silver NitrateCatalystHCID 962WaterSolvent2×HCID 8058HexaneSolvent

Conditions

Temperature
60 °C

Procedure

While stirring at 60° C., a solution of sodium peroxodisulfate (0.01 mol) in water (10 ml) was added to a heterogeneous mixture of silver nitrate (0.2 g) in water (40 ml) and 1,4-benzoquinone (0.01 mol) and 1-hexanol (0.04 mol) in hexane (5 ml). Extraction with diethyl ether followed by vaporization in vacuo yielded a residue which was purified using column chromatography on silica gel (eluting with hexane/diethylether).

Workup

  1. extractionExtraction with diethyl ether
  2. customyielded a residue which
  3. customwas purified

Sources & evidence

ORD record
ord-b27cedf97af84f45900fe2056df7b4d7
Source dataset
uspto-grants-2013_01
Patent number
US08350038B2

Reaction notes

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