HRID1811658

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID780

2,5-Dihydroxybenzeneacetic acid

C8H8O4

2 次

HCID1004

Phosphoric acid

H3O4P

结构：Cc1c(O)cc2c(c1C)O[C@](C)(CCC[C@H](C)CCC[C@H](C)CCCC(C)C)CC2

HCID92729

(+)-gamma-Tocopherol

C28H48O2

结构：CC(C)CCC[C@@H](C)CCC[C@@H](C)CCC[C@]1(C)CCc2cc(O)ccc2O1

HCID58866062

(2R)-3,4-Dihydro-2-methyl-2-[(4R,8R)-4,8,12-trimethyltridecyl]-2H-1-benzopyran-6-ol

C26H44O2

PRODUCTS

生成物

$结构：C/C(=C\COP(=O)([O-])OP(=O)([O-])[O-])CCC[C@H](C)CCC[C@H](C)CCCC(C)C$

HCID71728454

未命名化合物

$结构：C/C(=C\Cc1cc(O)c(C)c(C)c1O)CCC[C@H](C)CCC[C@H](C)CCCC(C)C$

HCID71768102

未命名化合物

$结构：C/C(=C\Cc1cc(O)cc(C)c1O)CCC[C@H](C)CCC[C@H](C)CCCC(C)C$

HCID71768135

未命名化合物

PROCEDURE

实验过程

Homogentisic acid in 0.1% H3PO4 (specific radioactivity 40 Ci/mmol). Phytyl pyrophosphate was synthesized as described by Joo, et al. (1973) Can J. Biochem. 51:1527. 2-methyl-6-phytylquinol and 2,3-dimethyl-5-phytylquinol were synthesized as described by Soll, et al. (1980) Phytochemistry 19:215. Homogentisic acid, α, β, δ, and γ-tocopherol, and tocol, were purchased commercially.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-0cc55701b82a4dbb90ec9e5ca2ac0db6
来源数据集: uspto-grants-2013_01
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08362324B2
来源说明: uspto-grants-2013_01

反应 SMILES

C(O)(=O)CC1C(=CC=C(C=1)O)O.[CH3:13][C:14]1[C:19]([OH:20])=[CH:18][C:17]2[CH2:21][CH2:22][C@:23]([CH2:26][CH2:27][CH2:28][C@@H:29]([CH2:31][CH2:32][CH2:33][C@@H:34]([CH2:36][CH2:37][CH2:38][CH:39]([CH3:41])[CH3:40])[CH3:35])[CH3:30])([CH3:25])[O:24][C:16]=2[C:15]=1[CH3:42].C[C@H](CCCC(C)C)CCC[C@H](CCC[C@@]1(C)OC2C=CC(O)=CC=2CC1)C.[OH:71][P:72]([OH:75])([OH:74])=[O:73]>>[O:73]([CH2:21]/[CH:22]=[C:23](/[CH2:26][CH2:27][CH2:28][C@@H:29]([CH2:31][CH2:32][CH2:33][C@@H:34]([CH2:36][CH2:37][CH2:38][CH:39]([CH3:41])[CH3:40])[CH3:35])[CH3:30])\[CH3:25])[P:72]([O:75][P:72]([O-:74])([O-:73])=[O:71])(=[O:74])[O-:71].[CH3:42][C:15]1[CH:14]=[C:19]([OH:20])[CH:18]=[C:17]([CH2:21]/[CH:22]=[C:23](/[CH2:26][CH2:27][CH2:28][C@@H:29]([CH2:31][CH2:32][CH2:33][C@@H:34]([CH2:36][CH2:37][CH2:38][CH:39]([CH3:41])[CH3:40])[CH3:35])[CH3:30])\[CH3:25])[C:16]=1[OH:24].[CH3:13][C:14]1[C:15]([CH3:42])=[C:16]([OH:24])[C:17]([CH2:21]/[CH:22]=[C:23](/[CH2:26][CH2:27][CH2:28][C@@H:29]([CH2:31][CH2:32][CH2:33][C@@H:34]([CH2:36][CH2:37][CH2:38][CH:39]([CH3:41])[CH3:40])[CH3:35])[CH3:30])\[CH3:25])=[CH:18][C:19]=1[OH:20]