Trifluoromethanesulfonic acid → HCID 22497309, compound

HRID 1816079Notes

Reaction equation

HRID 1816079 reaction equation
[F:1][C:2]([F:8])([F:7])[S:3]([OH:6])(=[O:5])=[O:4].[CH:9]12[CH2:15][CH:12]([CH2:13][CH2:14]1)[CH2:11][CH:10]2[Si:16]([CH3:19])([CH3:18])Cl>>[F:1][C:2]([F:8])([F:7])[S:3]([O:6][Si:16]([CH:10]1[CH2:11][CH:12]2[CH2:15][CH:9]1[CH2:14][CH2:13]2)([CH3:19])[CH3:18])(=[O:5])=[O:4]

Participants

3

Reactant 2

HCID 62406Trifluoromethanesulfonic acidHCID 2756665HCID 2756665, compound

Product 1

HCID 22497309HCID 22497309, compound

Conditions

Temperature
60 °C

Procedure

At room temperature, trifluoromethanesulfonic acid (7.50 g, 49.0 mmol) is added dropwise to 2-norbornyl-dimethylchlorosilane (9.50 g, 49.3 mmol), whose preparation is described in Example 1. The reaction mixture is heated to 60° C. for 10 h. The crude product is distilled under oil pump vacuum. 12.3 g (83%) of colorless, moisture-sensitive liquid having b.p. 100-105° C. (1 mbar) is obtained. Purity 93% (GC).

Workup

  1. distillationThe crude product is distilled under oil pump vacuum
  2. customis obtained

Sources & evidence

ORD record
ord-7b2d4a6c627b444f875a21011acd99d8
Source dataset
uspto-grants-2005_04
Patent number
US06881855B2

Reaction notes

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