Ethyl Acetate → HCID 22493493, compound

HRID 1816227Notes

Reaction equation

HRID 1816227 reaction equation
[N:1]1[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[NH:7][NH2:8].[CH3:9][S:10][C:11](SC)=[C:12]([C:16](=O)[CH3:17])[C:13](=[O:15])[CH3:14].C(OCC)(=O)C>[Cl-].[Na+].O>[CH3:17][C:16]1[N:7]([C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][N:1]=2)[N:8]=[C:11]([S:10][CH3:9])[C:12]=1[C:13](=[O:15])[CH3:14]

Participants

5

Reactant 3

HCID 8857Ethyl AcetateHCID 786452-HydrazinopyridineHCID 27785933-[bis(methylsulfanyl)methylidene]pentane-2,4-dione

Product 1

HCID 22493493HCID 22493493, compound

Reagents, catalysts & solvents 1

HCID 57417360Sodium chloride; waterSolvent

Conditions

Temperature
60 °C

Procedure

A mixture of pyridin-2-yl-hydrazine (1.0 equivalent) and 3-(bis-methylsulfanyl-methylene)-pentane-2,4-dione (1.0 equivalent) was stirred at 60° C. overnight. To the reaction mixture was added ethyl acetate and brine, the organic phase was washed by brine twice, dried over magensium sulfate, and filtered. The organic solvent was removed under reduced pressure to provide the title compound.

Workup

  1. washthe organic phase was washed by brine twice
  2. dry with materialdried over magensium sulfate
  3. filtrationfiltered
  4. customThe organic solvent was removed under reduced pressure

Sources & evidence

ORD record
ord-8fce0c7a6c7e43f681bb815d7cb7e9a5
Source dataset
uspto-grants-2005_04
Patent number
US06884804B2

Reaction notes

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