Ammonium Acetate → 3-Amino-5-isopropylcyclohex-2-en-1-one

HRID 1817802Notes

Reaction equation

[CH:1]([CH:4]1[CH2:9][C:8](=O)[CH2:7][C:6](=[O:11])[CH2:5]1)([CH3:3])[CH3:2].C([O-])(=O)C.[NH4+:16]>>[NH2:16][C:8]1[CH2:9][CH:4]([CH:1]([CH3:3])[CH3:2])[CH2:5][C:6](=[O:11])[CH:7]=1

Participants

Reactant 2

HCID 517165Ammonium Acetate

HCID 5661065-(Isopropyl)cyclohexane-1,3-dione

Product 1

HCID 577231043-Amino-5-isopropylcyclohex-2-en-1-one

Procedure

In analogy to (Baraldi, P. G.; Simoni, D.; Manfredini, S.; Synthesis 1983, (11) 902-903) 5-isopropylcyclohexane-1,3-dione was reacted with ammonium acetate to give the title compound as a colorless solid.

Sources & evidence

ORD record: ord-19f8b9ce366c4e9c85b642bcd1eaf4a3
Source dataset: uspto-grants-2009_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07598384B2

Reaction notes

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