Di-tert-butyl peroxide → HCID 178430960, compound

HRID 1817927Notes

Reaction equation

HRID 1817927 reaction equation
[C:1]([C:4]1([CH3:10])[N+:8]([O-:9])=[CH:7][CH2:6][CH2:5]1)(=[O:3])[NH2:2].C([C@H](N)C(O)=O)CC([NH:15][C@H](C(NCC(O)=O)=O)CSSC[C@H](NC(CC[C@H](N)C(O)=O)=O)C(NCC(O)=O)=O)=O.C(OOC(C)(C)C)(C)(C)C>P([O-])([O-])([O-])=O>[NH2:15][C:7]1[CH2:6][CH2:5][C:4]([C:1](=[O:3])[NH2:2])([CH3:10])[N+:8]=1[O-:9]

Participants

5

Reactant 3

HCID 8033Di-tert-butyl peroxideHCID 65359Glutathione DisulfideHCID 159527885-carbamoyl-5-methyl-1-pyrroline N-oxide

Product 1

HCID 178430960HCID 178430960, compound

Reagents, catalysts & solvents 1

HCID 1061PhosphateSolvent

Procedure

Trapping of GS. and t-BuO. radicals. 50 μL 0.1 M phosphate buffer solution containing 30 mM AMPO and 100 mM GSSG or (CH3)3CO—OC(CH3)3. The mixture was then transferred to 50 μL capillary tube and the radicals were generated by UV photolysis. EPR spectrum of the adduct was recorded over a 5 min time period.

Workup

  1. customThe mixture was then transferred to 50 μL capillary tube

Sources & evidence

ORD record
ord-b8cea38b5db048ecbdd0292875864d9a
Source dataset
uspto-grants-2009_10
Patent number
US07598400B2

Reaction notes

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