HuagongsheHuagongshe Chemistry Print Report · For research reference only
Isoprene → HCID 19842620, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Isoprene | HCID 6557 | — |
| Reactant | Styrene | HCID 7501 | — |
| Reactant | Tetrahydrofuran | HCID 8028 | — |
| Reactant | Butyllithium | HCID 178418339 | — |
| Solvent | Cyclohexane | HCID 8078 | — |
| Product | HCID 19842620 | HCID 19842620 | — |
Reaction Steps
The polymerization was conducted in cyclohexane by successively introducing styrene, isoprene and styrene into a reactor in this order in the presence of an n-butyllithium polymerization catalyst and tetrahydrofuran, to produce a styrene-isoprene-styrene triblock copolymer. The block copolymer thus produced was hydrogenated in cyclohexane in the presence of a Ziegler hydrogenation catalyst under a hydrogen pressure of 1.96 MPa (20 kg/cm2), to produce the titled hydrogenated triblock copolymer (hereinafter referred to merely as “block copolymer (II-1)”).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07601778B2 |
| Source dataset | uspto-grants-2009_10 |
| ORD ID | ord-a566b6efc4814082b2f15c89a965654e |
| Source note | uspto-grants-2009_10 |