1-Dodecanethiol → Sodium dodecane-1-thiolate

HRID 1821151Notes

Reaction equation

HRID 1821151 reaction equation
C[O-].[Na+:3].[CH2:4]([SH:16])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15]>CO>[CH2:4]([S-:16])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15].[Na+:3]

Participants

4

Reactant 2

HCID 81951-DodecanethiolHCID 10942334Sodium Methoxide

Product 1

HCID 23672953Sodium dodecane-1-thiolate

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

In another flask, sodium methoxide (1.43 g, 26 mmol) was dissolved in 10 ml methanol, and dodecanethiol (6.5 ml, 27 mmol) was added. The resulting solution was stirred at room temperature for 15 minutes. The solvent was then evaporated under reduced pressure at 90° C.

Workup

  1. customThe solvent was then evaporated under reduced pressure at 90° C.

Sources & evidence

ORD record
ord-9510c937aa0b4a378f0b2a3aa635ced6
Source dataset
uspto-grants-2009_10
Patent number
US07605290B2

Reaction notes

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