Methacrylic Acid → HCID 86588649, compound

HRID 1823706Notes

Reaction equation

HRID 1823706 reaction equation
[C:1]([OH:6])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:7]([O:12][CH2:13][CH:14]=[CH2:15])(=[O:11])[C:8]([CH3:10])=[CH2:9].[C:16]([O:20][CH2:21][C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1)(=[O:19])[CH:17]=[CH2:18].N(C(C)(CC(C)C)C#N)=NC(C)(CC(C)C)C#N>COCC(O)C.O>[C:1]([OH:6])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:7]([O:12][CH2:13][CH:14]=[CH2:15])(=[O:11])[C:8]([CH3:10])=[CH2:9].[C:16]([O:20][CH2:21][C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1)(=[O:19])[CH:17]=[CH2:18]

Participants

7

Reactant 4

HCID 4093Methacrylic Acid2×HCID 7274Allyl methacrylateHCID 75617Benzyl acrylateHCID 915372,2'-Azobis(2,4-dimethylvaleronitrile)

Product 1

HCID 86588649HCID 86588649, compound

Reagents, catalysts & solvents 2

HCID 962WaterSolventHCID 79001-Methoxy-2-propanolSolvent2×

Conditions

Temperature
70 °C

Procedure

427.5 parts of 1-methoxy-2-propanol were charged in a reaction vessel and heated under a nitrogen flow so that the internal temperature of the vessel was 70° C. Then a solution in which 18.5 parts of methacrylic acid, 46.5 parts of allyl methacrylate, 29.9 parts of benzyl acrylate (composition ratio of these methacrylic acid and esters was 28:48:24 in molar ratio), and 3.82 parts of V-65 (2,2′-azobis-(2,4′-dimethylvaleronitrile), manufactured by Wako Pure Chemical Co.) were dissolved in 427.5 parts of 1-methoxy-2-propanol was dropwise added into the vessel over a period of 2.5 hours. The mixture was agitated further for 2 hours under heating at 70° C. The obtained reaction liquid was poured into 5000 parts of water, and the resulting solid was separated by filtration and dried under vacuum to obtain a methacrylic acid/allyl methacrylate/benzyl acrylate terpolymer (terpolymer 3). The weight-average molecular weight of the terpolymer was 36,000 (converted as polystyrene).

Workup

  1. temperatureheated under a nitrogen flow so that the internal temperature of the vessel
  2. customwas 70° C
  3. additionwas dropwise added into the vessel over a period of 2.5 hours
  4. customThe obtained reaction liquid
  5. customthe resulting solid was separated by filtration
  6. customdried under vacuum

Sources & evidence

ORD record
ord-2a3319843e6f40d8996d8cdbcbc7873c
Source dataset
uspto-grants-2006_05
Patent number
US07041416B2

Reaction notes

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