CAS 2495-35-4 Benzyl acrylate (HCID 75617)

Names & identifiers

Preferred name: Benzyl acrylate
IUPAC: benzyl prop-2-enoate
English name: Benzyl acrylate
Molecular formula: C10H10O2
Molecular weight: 162.19

Names & synonyms

Benzyl acrylateBenzyl prop-2-enoate2-Propenoic acid, phenylmethyl esterMelcril 4085EINECS 219-673-9NSC 20964AI3-03836DTXSID1062467RefChem:118854DTXCID7037181219-673-9GCTPMLUUWLLESL-UHFFFAOYSA-N

Show more names

BenzylacrylatBenzyl acrylate, 97%, stabilizedAcrylic acid benzylLipid benzylacrylateBenzyl Acrylate,>99%Benzyl acrylate, 97%Phenylmethyl acrylate

2495-35-4Benzylacrylateacrylic acid benzyl esterbenzyl 2-propenoateSartomer SR 432Acrylic acid, benzyl esterMFCD00048147SR 432

Database identifiers

CAS: 2495-35-4
PubChem CID: 75617
DTXSID: DTXSID1062467
EC Number: 219-673-9
Nikkaji: J71.666I

Properties

Computed structural properties

XLogP: 2.6
Topological polar surface area: 26.3 Å²
Hydrogen bond donors: 0
Hydrogen bond acceptors: 2
Rotatable bonds: 4
Heavy atoms: 12
Formal charge: 0
Complexity: 157

Experimental & physicochemical properties

SpringerMaterials PropertiesOptical coefficient

Physicochemical properties

Melting point: 214 · 214-216 °C
Boiling point: 110 · 110-111°C 8mm
Density: 1 · 1,08 g/cm3
vapor pressure: 11.2 Pa · 11.2Pa at 25℃
refractive index: 1.518 · 1.5180
Flash point: 111 °C/8mm · 111°C/8mm
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly)
form: Liquid
color: Colorless
Water Solubility: Miscible with organic solvents and water.
InChI: InChI=1S/C10H10O2/c1-2-10(11)12-8-9-6-4-3-5-7-9/h2-7H,1,8H2
InChIKey: GCTPMLUUWLLESL-UHFFFAOYSA-N
SMILES: C(OCC1=CC=CC=C1)(=O)C=C
LogP: 2.436 · 2.436
CAS DataBase Reference: 2495 · 2495-35-4(CAS DataBase Reference)
EPA Substance Registry System: Benzyl acrylate (2495-35-4)
UNSPSC Code: 12352005 · 12352005
NACRES: 23 · NA.23
Symbol(GHS): 7 · GHS07,GHS09
Signal word: Warning
Hazard statements: 315 · H315-H335-H411
Precautionary statements: 261 · P261-P264-P271-P273-P280-P302+P352
target organs: Respiratory system
Risk Statements: 36 · 36/37/38
Safety Statements: 26 · 26-36/37/39-61-28
RIDADR: 3082 · UN3082
WGK Germany: 3 · WGK 3
TSCA: TSCA listed
HazardClass: 9 · 9
PackingGroup: III
HS Code: 29161290 · 29161290
Storage Class: 10 · 10 - Combustible liquids
Hazard Classifications: 2 Skin · Aquatic Chronic 2Skin Irrit. 2STOT SE 3
REACH Registrations: Active
Limited Quantities: 5 L · 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

Safety & regulation

GHS classification

GHS Classification · 6 items

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P272, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P333+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 170 reports by companies from 16 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

H315: Causes skin irritation [Warning Skin corrosion/irritation]

Hazard information

Regulatory Information · 3 items

Chemical: 2-Propenoic acid, phenylmethyl ester

Status: Active Update: 24-02-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/25890

2-Propenoic acid, phenylmethyl ester: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and Categories · 2 items

Skin Irrit. 2 (100%)

Eye irritation - category 2

Safety data

wgk: WGK 3
tsca: TSCA listed
ridadr: UN3082
hs_code: 29161290
risk_code: 36/37/38
Signal word: Warning
Symbol(GHS): GHS07,GHS09
safety_code: 26-36/37/39-61-28
hazard_class: 9
Storage Class: 10 - Combustible liquids
packing_group: III
target organs: Respiratory system
Hazard statements: H315-H335-H411
Limited Quantities: 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
REACH Registrations: Active
Hazard Classifications: Aquatic Chronic 2Skin Irrit. 2STOT SE 3
Precautionary statements: P261-P264-P271-P273-P280-P302+P352

Chemistry & industry

Uses & manufacturing

General Manufacturing Information2-Propenoic acid, phenylmethyl ester: ACTIVE

Applications · 3 items

UsesBenzyl Acrylate, is a reagent that can be used in the preparation of 2-(Phosphonomethyl)pentanedioic Acid (P353900), a selective glutamate carboxypeptidase 2 (GCP-II) inhibitor. It can also be used in the preparation of high refractive index polyacrylates.

UsesPreparation of high refractive index polyacrylates.Benzyl acrylate is used in the preparation of heptanoic acid benzyl ester. It is used to prepare polybenzylacrylate using azobisisobutyronitrile as initiator.

General DescriptionBenzyl acrylate is a polymer monomer that can be used to prepare high refractive index poly(benzyl acrylate).The main products of the pyrolysis of poly(benzyl acrylate) at temperatures of 260 ~300 °C are carbon dioxide, benzyl alcohol and oligomers. Moreover, the pyrolysis of poly(benzyl acrylate) seems to follow a similar pattern to that of poly(methyl acrylate).