Methyl Acrylate → HCID 69781572, compound

HRID 1824904Notes

Reaction equation

HRID 1824904 reaction equation
[C:1]1([CH:7]2[CH2:16][CH2:15][C:14]3[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=3)[CH:8]2[C:17]2[CH:22]=[CH:21][C:20](OS(C(F)(F)F)(=O)=O)=[CH:19][CH:18]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:31]([O:35][CH3:36])(=[O:34])[CH:32]=[CH2:33]>CC#N>[CH3:36][O:35][C:31](=[O:34])[CH:32]=[CH:33][C:20]1[CH:19]=[CH:18][C:17]([CH:8]2[C:9]3[C:14](=[CH:13][CH:12]=[CH:11][CH:10]=3)[CH2:15][CH2:16][CH:7]2[C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)=[CH:22][CH:21]=1

Participants

4

Reactant 2

HCID 7294Methyl AcrylateHCID 20821321HCID 20821321, compound

Product 1

HCID 69781572HCID 69781572, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

Prepared by Heck coupling 7b and methyl acrylate in accordance with the general method described in Example IV. Yield (76%); APcI m/z: 410 (M+H+CH3CN+, 100%).

Workup

  1. customPrepared by Heck
  2. customYield (76%)

Sources & evidence

ORD record
ord-29d99f6741964155aba6cefdd4b0266d
Source dataset
uspto-grants-2006_05
Patent number
US07045540B2

Reaction notes

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