Hydrogen iodide → HCID 22138046, compound

HRID 1827605Notes

Reaction equation

[CH:1]1[C:14]2[CH:13]=[C:12]([C:15]3[CH:16]=[C:17]([C:21]4(O)[C:34]5[CH:33]=[CH:32][CH:31]=[CH:30][C:29]=5[C:28]([C:36]5[CH:41]=[CH:40][CH:39]=[C:38]([C:42]6[C:43]7[C:48]([C:49]8[CH:50]=[CH:51][CH:52]=[CH:53][C:54]=8[CH:55]=6)=[CH:47][CH:46]=[CH:45][CH:44]=7)[CH:37]=5)(O)[C:27]5[C:22]4=[CH:23][CH:24]=[CH:25][CH:26]=5)[CH:18]=[CH:19][CH:20]=3)[C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.I.[PH2](O)=O>C(O)(=O)C>[CH:1]1[C:14]2[CH:13]=[C:12]([C:15]3[CH:16]=[C:17]([C:21]4[C:22]5[C:27]([C:28]([C:36]6[CH:41]=[CH:40][CH:39]=[C:38]([C:42]7[C:43]8[C:48]([C:49]9[CH:50]=[CH:51][CH:52]=[CH:53][C:54]=9[CH:55]=7)=[CH:47][CH:46]=[CH:45][CH:44]=8)[CH:37]=6)=[C:29]6[C:34]=4[CH:33]=[CH:32][CH:31]=[CH:30]6)=[CH:26][CH:25]=[CH:24][CH:23]=5)[CH:18]=[CH:19][CH:20]=3)[C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1

Participants

Conditions

Temperature: 100 °C

Procedure

9,10-bis(3-(9-Phenanthryl)phenyl)-9,10-dihydroxy-9,10-dihydroanthracene (5.2 g, 7.3 mmole) was suspended in acetic acid (120 ml). To the resultant suspension, a 57% hydroiodic acid (10 ml, 77 mmole, 10 eq) was added and the obtained mixture was stirred at 100° C. for 6 hours. To the reaction mixture, a 50% aqueous solution of hypophosphorous acid (40 ml) was added. The formed solid was separated by filtration and washed with water, methanol and acetone and a white solid (5.0 g, quant.) was obtained.

Workup

customThe formed solid was separated by filtration
washwashed with water, methanol and acetone
customa white solid (5.0 g, quant.) was obtained

Sources & evidence

ORD record: ord-8ecb8f81b0c04c17b53fe80b7692d8c9
Source dataset: uspto-grants-2006_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07053255B2

Reaction notes

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