m-Chloroperbenzoic acid → HCID 22049018, compound

HRID 1832745Notes

Reaction equation

HRID 1832745 reaction equation
[F:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][CH2:9][CH2:10][CH2:11][Cl:12])=[CH:4][CH:3]=1.C1C=C(Cl)C=C(C(OO)=[O:21])C=1>>[F:1][C:2]1[CH:3]=[CH:4][C:5]([S:8]([CH2:9][CH2:10][CH2:11][Cl:12])=[O:21])=[CH:6][CH:7]=1

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 2719971-[(3-chloropropyl)thio]-4-fluorobenzene

Product 1

HCID 22049018HCID 22049018, compound

Procedure

Prepared by Procedure S and Scheme AA using 3-chloropropyl 4-fluorophenyl sulfide and 1 eq m-CPBA: 1H NMR (400 MHz, CDCl3) δ 7.65–7.62 (m, 2H), 7.28–7.21 (m, 2H), 3.65 (m, 2H), 2.94 (m, 2H), 2.28 (m, 1H), 2.06 (m, 1H); ESMS m/e: 220.9 (M+H)+.

Workup

  1. customPrepared by Procedure S and Scheme AA

Sources & evidence

ORD record
ord-991e510a52874166b3c753637e2cf8c1
Source dataset
uspto-grants-2006_06
Patent number
US07067534B1

Reaction notes

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