2-Imidazolidinone → HCID 13031741, compound

HRID 1833590Notes

Reaction equation

HRID 1833590 reaction equation
[CH2:1]1[NH:6][C:4](=[O:5])[NH:3][CH2:2]1.[F:7][C:8]1[CH:13]=[CH:12][C:11]([S:14](Cl)(=[O:16])=[O:15])=[CH:10][CH:9]=1>>[F:7][C:8]1[CH:13]=[CH:12][C:11]([S:14]([N:3]2[CH2:2][CH2:1][NH:6][C:4]2=[O:5])(=[O:16])=[O:15])=[CH:10][CH:9]=1

Participants

3

Reactant 2

HCID 84532-ImidazolidinoneHCID 95884-Fluorobenzenesulfonyl chloride

Product 1

HCID 13031741HCID 13031741, compound

Procedure

The starting material required is prepared as follows: A mixture of 17.2 g of ethyleneurea and 19.5 g of p-fluorobenzene sulphonyl chloride is heated at 110° for 3 1/2 hrs. The residue is recrystallized from a mixture of methanol and water to afford 1-(4-fluorophenylsulphonyl)-2-oxo-tetrahydroimidazole which melts at 183°-185°.

Workup

  1. customThe starting material required is prepared
  2. temperatureis heated at 110° for 3 1/2 hrs
  3. customThe residue is recrystallized from a mixture of methanol and water

Sources & evidence

ORD record
ord-4de5117582824235a35cb15326101ee4
Source dataset
uspto-grants-1978_01
Patent number
US04066778

Reaction notes

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