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HRID1833943

反应详情

EQUATION

反应方程式

HRID 1833943 的结构方程式

REACTANTS

反应物

2
结构：CC1=CC=C(C(C)(C)CCC(=O)O)CC1
HCID21388144

未命名化合物

结构：[Li]C=C
HCID178506890

未命名化合物

PRODUCTS

生成物

1
结构：C=CC(=O)CCC(C)(C)C1=CC=C(C)CC1
HCID21388147

6-Methyl-6-(4-methylcyclohexa-1,3-dien-1-yl)hept-1-en-3-one

C15H22O

PROCEDURE

实验过程

reacting the 4-methyl-4(4-methyl-1,3-cyclohexadien-1-yl)pentanoic acid with vinyl lithium to form the intermediate 6-methyl-6(4-methyl-1,3-cyclohexadien-1-yl)hepten-3-one which is converted via an internal Diels-Alder reaction to form the 1,7,7-trimethyltricyclo[6.2.2.03,8 ]dodec-9-en-4-one.