HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 21388144, compound → 6-Methyl-6-(4-methylcyclohexa-1,3-dien-1-yl)hept-1-en-3-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 21388144 | HCID 21388144 | — |
| Reactant | HCID 178506890 | HCID 178506890 | — |
| Product | 6-Methyl-6-(4-methylcyclohexa-1,3-dien-1-yl)hept-1-en-3-one | HCID 21388147 | — |
Reaction Steps
reacting the 4-methyl-4(4-methyl-1,3-cyclohexadien-1-yl)pentanoic acid with vinyl lithium to form the intermediate 6-methyl-6(4-methyl-1,3-cyclohexadien-1-yl)hepten-3-one which is converted via an internal Diels-Alder reaction to form the 1,7,7-trimethyltricyclo[6.2.2.03,8 ]dodec-9-en-4-one.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04067906 |
| Source dataset | uspto-grants-1978_01 |
| ORD ID | ord-9302cee14a134459b2b59d14c5d4f149 |
| Source note | uspto-grants-1978_01 |