Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Aniline | HCID 6115 | — |
| Reactant | 1-Naphthol | HCID 7005 | — |
| Reactant | Diphenoxyphosphanolate | HCID 23418553 | — |
| Solvent | Water | HCID 962 | — |
| Product | Phenyl-1-naphthylamine | HCID 7013 | 85% |
Reaction Steps
288 parts of α-naphthol, 205 parts of aniline and 10 parts of diphenyl phosphite are mixed and heated to 197° C. The elimination of water commences at this temperature and has ended when the internal temperature is 235° C. 31 parts of water are removed in the course of 8 hours. After distilling off excess α-naphthol and aniline, 372 parts of phenyl-α-naphthylamine are obtained at a boiling point of 202° - 204° C/5 mm Hg; the product has a melting point of 55° - 58° C and corresponds to a yield of 85% of theory.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04067903 |
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| Source dataset | uspto-grants-1978_01 |
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| ORD ID | ord-42755be7d4cf4d58b23d741410ba3560 |
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| Source note | uspto-grants-1978_01 |
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