Chlorine → HCID 20373876, compound

HRID 1834698Notes

Reaction equation

HRID 1834698 reaction equation
[O:1]=[C:2]1[C:10]2[C:5](=[CH:6][C:7]([O:13][CH:14]([CH3:18])[C:15]([OH:17])=[O:16])=[C:8]([Cl:12])[C:9]=2[Cl:11])[CH2:4][CH:3]1[CH2:19][CH3:20].[Cl:21]Cl>Cl.C(O)(=O)C>[O:1]=[C:2]1[C:10]2[C:5](=[CH:6][C:7]([O:13][CH:14]([CH3:18])[C:15]([OH:17])=[O:16])=[C:8]([Cl:12])[C:9]=2[Cl:11])[CH2:4][C:3]1([CH2:19][CH3:20])[Cl:21]

Participants

5

Reactant 2

HCID 24526ChlorineHCID 20373914HCID 20373914, compound

Product 1

HCID 20373876HCID 20373876, compound

Reagents, catalysts & solvents 2

HCID 313Hydrochloric AcidCatalystHCID 176Acetic AcidSolvent

Procedure

By following substantially the procedure described in Example 12, Step B, and using as the reactants 2-(1-oxo-2-ethyl-6,7-dichloro-5-indanyloxy)propionic acid (3.17 g., 0.01 mole), glacial acetic acid (50 ml.), chlorine (710 mg., 0.01 mole) and concentrated hydrochloric acid (1 drop) there is obtained 2-(1-oxo-2-ethyl-2,6,7-trichloro-5-indanyloxy)-propionic acid.

Sources & evidence

ORD record
ord-81edfaea91f04f0592ce8c08394fd089
Source dataset
uspto-grants-1978_01
Patent number
US04070539

Reaction notes

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