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HRID1834986

反应详情

EQUATION

反应方程式

HRID 1834986 的结构方程式

REACTANTS

反应物

2
结构：C[C@]12CC[C@H]3[C@@H](CCC4=CC(=O)CC[C@@]43COC3CCCCO3)[C@@H]1CCC2=O
HCID10091561

未命名化合物

结构：C[C@]12CC[C@H]3[C@@H](CCC4=CC(=O)CC[C@@]43CO[Si](C)(C)C)[C@@H]1CCC2=O
HCID22801497

未命名化合物

PRODUCTS

生成物

2
结构：C[C@]12CC[C@H]3[C@@H](CC[C@H]4CC(=O)CC[C@@]43COC3CCCCO3)[C@@H]1CCC2=O
HCID22801526

未命名化合物

结构：C[C@]12CC[C@H]3[C@@H](CC[C@H]4CC(=O)CC[C@@]43CO[Si](C)(C)C)[C@@H]1CCC2=O
HCID22801527

未命名化合物

PROCEDURE

实验过程

Substituting 17β-hydroxy-4,6α,17α-trimethyl-4-androstene-3,19-dione, 17β-hydroxy-4,6α,17α-trimethyl-4-androstene-3,19-dione acetate, 19-tetrahydropyranyloxy-4-androstene-3,17-dione, 19-trimethylsiloxy-4-androstene-3,17-dione and 6α-methyl-19-(2'-tetrahydropyranyloxy)-4-androstene-3,17-dione for the 4,6α,17α-trimethyl-17β,19-di(2'-tetrahydropyranyloxy)-4-androsten-3-one above results in the preparation of 17β-hydroxy-4,6α,17α-trimethyl-5α-androstane-3,19-dione, 17β-hydroxy-4,6α,17α-trimethyl-5α-androstane-3,19-dione acetate, 19-tetrahydropyranyloxy-5α-androstane-3,17-dione, 19-trimethylsiloxy-5α-androstane-3,17-dione and 6α-methyl-19-(2'-tetrahydropyranyloxy)-5α-androstane-3,17-dione, respectively.