Ethanol → HCID 69303462, compound

HRID 1835062Notes

Reaction equation

HRID 1835062 reaction equation
[CH3:1][C:2]([C@H:4]1[C@H:9]([CH3:10])[CH2:8][CH2:7][CH2:6][C:5]1([CH3:12])[CH3:11])=[O:3].[CH3:13][CH2:14]O>>[CH3:12][C:5]1([CH3:11])[CH2:6][CH2:7][CH2:8][C@@H:9]([CH3:10])[C@@H:4]1[C:2](=[O:3])[CH:1]=[CH:13][CH3:14]

Participants

3

Reactant 2

HCID 702EthanolHCID 10434152842-33-8

Product 1

HCID 69303462HCID 69303462, compound

Procedure

The reaction was carried out in exactly the same manner as Reference Example 6 using 37 g of the (1S,6R)-2,2,6-trimethylcyclohexyl methyl ketone (1a) synthesized in Example 2 to obtain 29 g of (1S,6R)-1-(2,2,6-trimethylcyclohexyl)-2-buten-1-one (10a) (b.p.: 73-75° C./19.95 Pa (0.15 torr), [α]D=+15.52° (c 1.00, EtOH, 24° C.).

Sources & evidence

ORD record
ord-7d916157191a48008230f26fa7965810
Source dataset
uspto-grants-2004_08
Patent number
US06770618B2

Reaction notes

Loading…