Dimethylformamide → HCID 178424119, compound

HRID 1835558Notes

Reaction equation

HRID 1835558 reaction equation
Br[C:2]1[CH:7]=[C:6]([CH3:8])[CH:5]=[CH:4][C:3]=1N.C(O[C:13]([SH:15])=[S:14])C.[K].C[N:18](C=O)C>>[SH:15][C:13]1[S:14][C:2]2[CH:3]=[CH:4][CH:5]=[C:6]([CH3:8])[C:7]=2[N:18]=1

Participants

5

Reactant 4

HCID 6228DimethylformamideHCID 8823Ethyl xanthateHCID 114222-Bromo-4-methylanilineHCID 5462222Potassium

Product 1

HCID 178424119HCID 178424119, compound

Procedure

The title compound was prepared using the method of example 239, starting with 2-bromo-4-methyl-phenylamine (Acros) (27.9 g), O-ethylxanthic acid, potassium salt (Lancaster, 54 g) in DMF (250 mL). The mercaptobenzothiazole 340 was obtained as an pale brown solid (27 g). Recrystalization from CHCl3 gave pinkish white crystals (20 g).

Workup

  1. customThe title compound was prepared

Sources & evidence

ORD record
ord-4bf5332a5d4e4fbda78e7539a07046de
Source dataset
uspto-grants-2004_08
Patent number
US06770648B2

Reaction notes

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