Oxetane, 3,3-bis(chloromethyl)- → HCID 66915753, compound

HRID 1837419Notes

Reaction equation

HRID 1837419 reaction equation
C1[O:4][CH2:3]C1.CC1(C)COC1.ClCC1(CCl)COC1.[CH2:19]([C:21]1([CH2:25][O:26][C:27]2[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=2)[CH2:24][O:23][CH2:22]1)[CH3:20].C(C1(CO)COC1)C.[CH2:41]([C:43]1([CH2:47][O:48][CH2:49][C:50]2[CH:55]=[CH:54][CH:53]=[CH:52][C:51]=2[CH2:56][O:57][CH2:58][C:59]2([CH2:63][CH3:64])[CH2:62][O:61][CH2:60]2)[CH2:46][O:45][CH2:44]1)[CH3:42]>>[CH2:41]([C:43]1([CH2:47][O:48][CH2:49][C:50]2[C:51]([CH2:56][O:57][CH2:58][C:59]3([CH2:63][CH3:64])[CH2:62][O:61][CH2:60]3)=[C:52]([CH2:27][O:26][CH2:25][C:21]3([CH2:19][CH3:20])[CH2:24][O:23][CH2:22]3)[CH:53]=[CH:54][CH:55]=2)[CH2:46][O:45][CH2:44]1)[CH3:42].[CH2:63]([C:59]1([CH2:58][O:57][CH2:56][C:51]2[CH:52]=[CH:53][CH:54]=[CH:55][C:50]=2[O:4][C:3]2[CH:28]=[CH:29][CH:30]=[CH:31][C:32]=2[CH2:27][O:26][CH2:25][C:21]2([CH2:19][CH3:20])[CH2:22][O:23][CH2:24]2)[CH2:60][O:61][CH2:62]1)[CH3:64]

Participants

8

Reactant 6

HCID 6550Oxetane, 3,3-bis(chloromethyl)-HCID 10423OxetaneHCID 23352Oxetane, 3,3-dimethyl- (9CI)HCID 76444Oxt-101HCID 218678333-Ethyl-3-(phenoxymethyl)oxetaneHCID 669158323,3'-[1,2-Phenylenebis(methyleneoxymethylene)]bis(3-ethyloxetane)

Product 2

HCID 66915753HCID 66915753, compoundHCID 66915905HCID 66915905, compound

Procedure

Specific examples of the compound (d) include trimethylene oxide, 3,3-dimethyloxetane, 3,3-bis(chloromethyl)oxetane, 3-ethyl-3-phenoxymethyloxetane, 3-ethyl-3-hydroxymethyloxetane (EOXA, trade name, produced by Toa Gosei), bis[(3-ethyl-3-oxetanylmethoxy)methyl]benzene (also called xylylene dioxetane; XDO, trade name, produced by Toa Gosei), tri[(3-ethyl-3-oxetanylmethoxy)methyl]benzene, bis[(3-ethyl-3-oxetanylmethoxy)methylphenyl]ether, (3-ethyl-3-oxetanylmethoxy)oligodimethylsiloxane, and compounds containing a plurality of oxetane rings having a high molecular mass, specifically, oxetane oligomer (Oligo-OXT, trade name, produced by Toa Gosei), 2-oxaspiro[3.5]nonane, 7-methyl-2-oxaspiro[3.5]nonane, spiro[adamantane-2,3′-oxetane], spiro[bicyclo[2.2.1]heptane-2,3′-oxetane], spiro[bicyclo[2.2.2]octane-2,3,-oxetane], spiro[7-oxabicyclo[2.2.1]heptane-2,3′-oxetane], 2-oxaspiro[3.5]non-6-ene, 5-methyl-2-oxaspiro[3.5]non-6-ene, spiro[bicyclo[2.2.1]hept-5-ene-2,3′-oxetane], spiro[3-methylbicyclo[2.2.1]hept-5-ene-2,3′-oxetane], 5-methyl-2-oxaspiro[3.5]nonane and spiro[3-methylbicyclo[2.2.1]heptane-2,3′-oxetane.

Sources & evidence

ORD record
ord-8252e3f144a74b038237a398de9c1d00
Source dataset
uspto-grants-2004_08
Patent number
US06783840B2

Reaction notes

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